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L-Serine and Sphingolipids (SL) The first and rate-limiting step in de novo synthesis of SL (ceramides, phosphosphingolipids and glycosphingolipids) is condensation of fatty acyl-CoA (preferred substrate is palmitic acid) and L-serine to form 3-ketosphinganine (3-keto-dihydrosphingosine) in a reaction catalyzed by serine palmitoyltransferase
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